Visible light-driven CO2 reduction with a Ru polypyridyl complex bearing an N-heterocyclic carbene moiety
Visible light-driven CO2 reduction with a Ru polypyridyl complex bearing an N-heterocyclic carbene moiety
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使用带有 N-杂环卡宾部分的 Ru 聚吡啶复合物实现可见光驱动的 CO2 还原
DOI：
10.1039/d2cc00657j
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发表时间：
2022
影响因子：
4.9
通讯作者：
Masaoka Shigeyuki
中科院分区：
文献类型：
--
作者：
Watanabe Taito;Saga Yutaka;Kosugi Kento;Iwami Hikaru;Kondo Mio;Masaoka Shigeyuki
成功地合成了一种新型的钌多吡啶配合物，并对其进行了表征。该配合物在可见光区显示出来自卡宾配体强供电子特性的强吸收带，并有效地催化可见光驱动的CO2还原，反应速率为36.7 h-1。
A novel Ru polypyridyl complex with an N-heterocyclic carbene ligand was successfully synthesised and characterised. The complex exhibited an intense absorption band in the visible-light region derived from the strong electron-donating character of the carbene ligand, and efficiently catalysed the visible light-driven CO2 reduction with the reaction rate of 36.7 h−1.