Nitrogen-doped carbon materials as a promising platform toward the efficient catalysis for hydrogen generation
Nitrogen-doped carbon materials as a promising platform toward the efficient catalysis for hydrogen generation
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DOI：
10.1016/j.apcata.2018.11.034
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发表时间：
2019-02
期刊：
影响因子：
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通讯作者：
D. Salinas-Torres;M. Navlani-García;K. Mori;Yasutaka Kuwahara;H. Yamashita
中科院分区：
文献类型：
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作者：
D. Salinas-Torres;M. Navlani-García;K. Mori;Yasutaka Kuwahara;H. Yamashita
氮掺杂碳材料作为金属基催化剂和无金属催化体系的载体，具有突出的特点，已成为一种多用途的候选材料。它们的使用传统上与电化学应用有关，但在过去十年中，这些材料显示其优点的应用数量呈指数级增长。特别地，基于负载在氮掺杂的碳材料上的金属纳米颗粒的催化剂已经显示出对于重要的催化反应是有吸引力的，因为它们显示出由良好分散的、稳定的和电子促进的纳米颗粒以及由载体的改性的酸碱性质赋予的增强的性能。本综述的重点是最近取得的突破，这些催化体系中的一些最具代表性的氢载体分子的氢气生产突出的影响，在支持矩阵中的氮的掺入。
Nitrogen-doped carbon materials have emerged as versatile candidates with outstanding features as both support of metal-based catalysts and metal-free catalytic systems. Their use has been traditionally linked to electrochemical applications, but the number of applications in which these materials show their virtues has been exponentially increasing in the last decade. Particularly, catalysts based on metal nanoparticles supported on nitrogen-doped carbon materials have shown to be attractive for important catalytic reactions as they display enhanced performances endowed by well-dispersed, stabilized and electronically promoted nanoparticles as well as by the modified acid-base properties of the support. The present review is focused on the most recent breakthroughs achieved by these catalytic systems in the hydrogen production from some of the most representative hydrogen carrier molecules by highlighting the effect of the incorporation of nitrogen in the support matrix.