Aromatic hydroxylation by molecular oxygen performed by mononuclear benzoato iron(II) complexes and preparation of new iron(III) complex with two minus ligand
Aromatic hydroxylation by molecular oxygen performed by mononuclear benzoato iron(II) complexes and preparation of new iron(III) complex with two minus ligand
复制标题
DOI：
10.1016/j.inoche.2007.12.032
复制
发表时间：
2008-04-01
影响因子：
3.8
通讯作者：
Okamoto, Ken-ichi
中科院分区：
文献类型：
--
作者：
Fujisawa, Kiyoshi;Tada, Naoki;Okamoto, Ken-ichi
报道了苯甲酸铁(II)配合物[Fe-II{Hb(3-Ph-5-MePZ)(3)(ETA(1)-O2CC6H4-p-X)(3-Ph-5-MepzH)](2a(X=Cl)，2b(X=H)，2c(X=OMe))中分子氧插入芳香族C-H键的新反应。用X-射线单晶衍射法测定了羟基配合物[Fe-Ⅲ{HB(3-OPh-5-Mepz)(3-Ph-5-MepZ)(2))(eta(1)-O2CC6H4-p-X)(3-Ph-5-MepzH)](3a(X=Cl)，3b(X=H)，3c(X=OMe))的结构；用3a与碱反应合成了一种新的紫色铁(III)配合物[Fe-{HB(3-OPh-5-Mepz)(3-Ph-5-MePZ)(2)}(3-Ph-5-Mepz)](4)]。(C)2008爱思唯尔B.V.保留所有权利。
A novel oxygen insertion reaction by molecular oxygen into an aromatic C-H bond in benzoato iron(II) complexes [Fe-II {HB(3-Ph-5-MePZ)(3))(eta(1) -O2CC6H4-p-X)(3-Ph-5-MepzH)] (2a (X = Cl), 2b (X = H), and 2c (X = OMe)) is described. The structures of the hydroxylated complexes [Fe-III {HB(3-OPh-5-Mepz)(3-Ph-5-MepZ)(2))(eta(1)-O2CC6H4-p-X)(3-Ph-5-MepzH)] (3a (X=Cl), 3b (X=H), and 3c (X = OMe)) were determined by X-ray crystallography and other spectroscopic characterizations were performed; one of the phenyl rings in the hydrotris(pyrazolyl)borate ligand was hydroxylated. A new purple colored iron(III) complex [Fe-III {HB(3-OPh-5-Mepz)(3-Ph-5-MePZ)(2)}(3-Ph-5-Mepz)] (4), which was obtained by the reaction of 3a with base, is also characterized. (C) 2008 Elsevier B.V. All rights reserved.