Effect of thermal treatment on the structure of multi-walled carbon nanotubes
Effect of thermal treatment on the structure of multi-walled carbon nanotubes
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DOI：
10.1007/s11051-006-9113-6
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发表时间：
2006-10-01
影响因子：
2.5
通讯作者：
Gogotsi, Y.
中科院分区：
文献类型：
--
作者：
Behler, K.;Osswald, S.;Gogotsi, Y.
The effects of vacuum annealing and oxidation in air on the structure of multi-walled carbon nanotubes (MWCNTs) produced by a large-scale catalytic chemical vapor deposition (CCVD) process are studied using Raman spectroscopy and transmission electron microscopy (TEM). A detailed Raman spectroscopic study of as-produced nanotubes has also been conducted. While oxidation in air up to 400 degrees C removes disordered carbon, defects in tube walls are produced at higher temperatures. TEM reveals that MWCNTs annealed at 1,800 degrees C and above become more ordered than as-received tubes, while the tubes annealed at 2,000 degrees C exhibit polygonalization, mass transfer and over growth. The change in structure is observable by the separation of the Raman G and D' peaks, a lower R-value (I-D/I-G ratio), and an increase in the intensity of the second order peaks. Using wavelengths from the deep ultraviolet (UV) range (5.08 eV) extending into the visible near infrared (IR) (1.59 eV), the Raman spectra of MWCNTs reveal a dependence of the D-band position proportional to the excitation energy of the incident laser energies.
