Observation of magnetic interactions between localized 4f- and itinerant π-electrons in a single crystal of cationic bisphthalocyanine complexes containing diluted spin centres.
Observation of magnetic interactions between localized 4f- and itinerant π-electrons in a single crystal of cationic bisphthalocyanine complexes containing diluted spin centres.
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观察含有稀释自旋中心的阳离子双酞菁配合物单晶中局域 4f 电子和巡回 π 电子之间的磁相互作用。
DOI：
10.1039/c7dt02656k
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发表时间：
2017
影响因子：
4
通讯作者：
N. Ishikawa
中科院分区：
文献类型：
--
作者：
T. Fukuda;Shu Onodera;H. Watanabe;K. Shirasaki;A. Fuyuhiro;T. Yamamura;N. Ishikawa
通过在存在外部磁场的情况下测量晶体的电导率，在双酞菁钇 (iii)/铽 (iii) 四氟硼酸盐 ([Pc2Y0.95Tb0.05][BF4]) 单晶中观察到局域 4f 电子和巡回 π 电子之间的磁性 f-π 相互作用。
Magnetic f-π interactions between localized 4f-electrons and itinerant π-electrons have been observed in a single crystal of bisphthalocyaninato yttrium(iii)/terbium(iii) tetrafluoroborate ([Pc2Y0.95Tb0.05][BF4]) by measuring electrical conductivity of the crystal in the presence of an external magnetic field.
影响因子：
15
作者：
Ishikawa, N;Sugita, M;Kaizu, Y
通讯作者：
Kaizu, Y