CONTROL AND APPLICATIONS OF REMOTE ASYMMETRIC INDUCTION USING ALLYLMETAL REAGENTS
CONTROL AND APPLICATIONS OF REMOTE ASYMMETRIC INDUCTION USING ALLYLMETAL REAGENTS
复制标题
烯丙基金属试剂远程不对称感应的控制与应用
DOI：
10.1039/a603881f
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发表时间：
1997
影响因子：
4.9
通讯作者：
E. Thomas
中科院分区：
文献类型：
--
作者：
E. Thomas
羟基和烷氧基取代的烯丙基锡烷的处理
卤化锡（IV）影响金属转移和立体选择性形成
烯丙基锡三卤化物。这些与衍生自的醛和亚胺反应
具有有用水平的远程不对称诱导的乙醛酸盐。方面
this chemistry are discussed, together with the conversion of the products
分解为四氢呋喃和二氢吡喃。
Treatment of hydroxy- and alkoxy-substituted allylstannanes with
tin(IV) halides effects transmetallation and the stereoselective formation
of allyltin trihalides. These react with aldehydes and imines derived from
glyoxylates with useful levels of remote asymmetric induction. Aspects of
this chemistry are discussed, together with the conversion of the products
into tetrahydrofurans and dihydropyrans.