HYDROBORATION POLYMERIZATION .1. SYNTHESIS OF ORGANOBORON POLYMERS BY POLYADDITION BETWEEN DIENE AND MONOALKYLBORANE
HYDROBORATION POLYMERIZATION .1. SYNTHESIS OF ORGANOBORON POLYMERS BY POLYADDITION BETWEEN DIENE AND MONOALKYLBORANE
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DOI：
10.1021/ma00002a001
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发表时间：
1991-01-21
期刊：
影响因子：
5.5
通讯作者：
SAEGUSA, T
中科院分区：
文献类型：
--
作者：
CHUJO, Y;TOMITA, I;SAEGUSA, T
本文报道了二烯与单烷基硼烷的加聚反应，即“硼氢化聚合”。 在四氢呋喃中，在0 ℃和氮气氛下进行己基硼烷与1，7-辛二烯的反应，以制备有机硼聚合物。 所得聚合物的分子量随着进料比接近1而增加。 以1，9-癸二烯、对二乙烯基苯、对二烯丙基苯、乙二醇的双烯丙基醚、1，4-丁二醇、三甘醇、对苯二酚和双酚A为二烯组分，进行硼氢化聚合，得到相应的有机硼聚合物。 考察了所得聚合物的热稳定性和氧化稳定性。 这些聚合物与常规的“三烷基硼烷”相比对空气稍微更稳定。
We report here a polyaddition between diene and monoalkylborane, that is, "Hydroboration Polymerization". The reaction of thexylborane with 1,7-octadiene was carried out in tetrahydrofuran at 0-degrees-C under nitrogen atmosphere to produce an organoboron polymer. The molecular weight of the polymer obtained increased as the feed ratio to unity was approached. As a diene component, 1,9-decadiene, p-divinylbenzene, p-diallylbenzene, bis(allyl ether)s of ethylene glycol, 1,4-butanediol, triethylene glycol, hydroquinone, and bisphenol A were used in this hydroboration polymerization to give the corresponding organoboron polymers. The thermal and oxidative stabilities of the obtained polymers were examined. These polymers were a little more stable toward air in comparison with conventional "trialkylboranes".