Supported gold nanoparticle catalyst for the selective oxidation of silanes to silanols in water
Supported gold nanoparticle catalyst for the selective oxidation of silanes to silanols in water
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DOI：
10.1039/b910208f
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发表时间：
2009-01-01
影响因子：
4.9
通讯作者：
Kaneda, Kiyotomi
中科院分区：
文献类型：
--
作者：
Mitsudome, Takato;Noujima, Akifumi;Kaneda, Kiyotomi
羟基磷灰石负载的金纳米粒子(AuHAP)可以作为高效、可重复使用的催化剂在水中将各种硅烷氧化成硅醇，这是首次在无有机溶剂的条件下以水为催化剂选择性合成脂肪族硅醇的方法。
Hydroxyapatite-supported gold nanoparticles (AuHAP) can act as highly efficient and reusable catalysts for the oxidation of diverse silanes into silanols in water; this is the first catalytic methodology for the selective synthesis of aliphatic silanols using water under organic-solvent-free conditions.