η6-Arene complexes of Ni(II), efficient catalysts for 1,3-butadiene and styrene polymerization
η6-Arene complexes of Ni(II), efficient catalysts for 1,3-butadiene and styrene polymerization
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DOI：
10.1039/b209838e
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发表时间：
2003-01-01
影响因子：
4.9
通讯作者：
Passaglia, E
中科院分区：
文献类型：
--
作者：
Cámpora, J;Conejo, MD;Passaglia, E
报道了制备组成为 [Ni(eta(6)-ArX)(eta(3)-C3H5)](+)[BAr'(4)](-) (X = OH, H) 的 Ni(II) 阳离子芳烃配合物的简单程序。这些化合物被证明是 1,3-丁二烯和苯乙烯聚合的高活性催化剂。
A simple procedure for the preparation of cationic arene complexes of Ni(II) of composition [Ni(eta(6)-ArX)(eta(3)-C3H5)](+)[BAr'(4)](-) (X = OH, H) is reported. These compounds are shown to behave as highly active catalysts for the polymerization of 1,3-butadiene and styrene.