Retention of Pt→B bonding in oxidative addition reactions of the platinaboratrane [Pt(PPh3){B(mt)3}](Pt→B)10 (mt = methimazolyl)
Retention of Pt→B bonding in oxidative addition reactions of the platinaboratrane [Pt(PPh3){B(mt)3}](Pt→B)10 (mt = methimazolyl)
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DOI：
10.1021/om700835h
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发表时间：
2008-02-11
期刊：
影响因子：
2.8
通讯作者：
Willis, Anthony C.
中科院分区：
文献类型：
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作者：
Crossley, Ian R.;Hill, Anthony F.;Willis, Anthony C.
如第一个结构表征的铂硼烷[PtH(PPh3){B(Mt)(3)}][Pth(PPh3){B(Mt)(3)}][Pth(PPh3){B(Mt)(3)}][PtI2{B(Mt)(3)}](8)和[PtI2{B(Mt)(3)}](Pt&Gt；B)(8)所示，铂硼杂环[Pt(PPh3){B(Mt)(3)(10)(Mt=Mt)(10)](Mt=Mt)(8)和[PtI2{B(Mt)(3)}][PtI2{B(Mt)(3)}](8)和[PtI2{B(Mt)(3)}](Pt&Gt；B)(8)说明了铂硼杂环[PtH(PPh3){B(Mt)(3)}][PtI2{B(Mt)(3)}](8)。
The platinaboratrane [Pt(PPh3){B(mt)(3)}](Pt -> B)(10) (mt = methimazolyl) is prone to oxidative addition reactions with a range of substrates (Cl-2, Br-2, I-2, HCl, CH3I) without disrupting the platinum-boron dative bond, as illustrated by the first structurally characterized platinaboratranes [PtH(PPh3){B(mt)(3)}]Cl(Pt -> B)(8) and [PtI2{B(mt)(3)}](Pt -> B)(8).