The bromine doping of polyacetylene
The bromine doping of polyacetylene
复制标题
聚乙炔的溴掺杂
DOI：
10.1016/s0378-4371(02)01754-5
复制
发表时间：
2003
影响因子：
3.3
通讯作者：
C. Chiang
中科院分区：
文献类型：
--
作者：
C. Chiang
介绍了Chiang和白川等人进行的聚乙炔溴掺杂的原始实验。这个简单的开创性实验通过发现金属导电合成有机聚合物以及验证和证明有机聚合物中的掺杂概念而影响了物理和化学。虽然聚乙炔的分子式很简单，但这种分子表现出复杂的行为，不仅在聚合物科学中，而且在量子物理学中都有重要的工作。用来描述聚乙炔简单但独特的一维结构的孤子理论启发了许多新的量子概念，用于更复杂的导电聚合物。对模型复杂导电聚合物的持续研究可以在分子水平上更好地理解量子电子器件。
The original experiment of the bromine doping of polyacetylene performed by Chiang and Shirakawa is described. This simple, seminal experiment impacted physics and chemistry through the discovery of metallic conducting synthetic organic polymers and the verification and demonstration of the doping concept in organic polymers. Although the molecular formula of polyacetylene is simple, this molecule exhibits complex behavior and fueling significant work not only in polymer science, but also in quantum physics. The soliton theories used to describe polyacetylene's simple but unique 1-D structure inspired many new quantum concepts for more complicated conducting polymers. The continuing study of model complex conducting polymers could lead to a better understanding of quantum electronic devices at the molecular level.