Theory of Voltammetric Current of Electron Transfer across Liquid/Liquid Interface
Theory of Voltammetric Current of Electron Transfer across Liquid/Liquid Interface
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液/液界面电子转移伏安电流理论
DOI：
10.5189/revpolarography.49.219
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发表时间：
2003
期刊：
影响因子：
--
通讯作者：
M. Senda
中科院分区：
文献类型：
--
作者：
M. Senda
在某些合理的假设下，推导了油（O）/水（W）界面电子转移（ET）的法向脉冲伏安电流的理论方程。这些理论方程被认为有助于研究反应机理，无论是 O/W 界面处的非均相 ET 还是与跨界面离子转移相关的均相 ET。将理论扩展到电位扫描伏安法或循环伏安法似乎是可行的。
Theoretical equations of normal-pulse voltammetric current of the electron transfer (ET) across oil (O)/water(W) interface have been derived under certain, reasonable assumptions. These theoretical equations are considered to be useful to investigate the reaction mechanism whether it is the heterogeneous ET at O/W interface or the homogeneous ET associated with ion transfer across the interface. Extension of the theory to potential sweep voltammetry or cyclic voltammetry appears feasible.