Nanocage-Based Porous Metal-Organic Frameworks Constructed from Icosahedrons and Tetrahedrons for Selective Gas Adsorption
Nanocage-Based Porous Metal-Organic Frameworks Constructed from Icosahedrons and Tetrahedrons for Selective Gas Adsorption
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由二十面体和四面体构建的基于纳米笼的多孔金属有机框架用于选择性气体吸附
DOI：
10.1021/acsami.9b05655
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发表时间：
2019
影响因子：
9.5
通讯作者：
Li Yun Wu
中科院分区：
文献类型：
--
作者：
Zhang Da Shuai;Zhang Yong Zheng;Zhang Xiuling;Wang Fei;Zhang Jian;Hu Hui;Gao Jun;Yan Hui;Liu Hui Ling;Ma Hui Yan;Geng Long Long;Li Yun Wu
采用水热法合成了两种纳米结构的多孔Ni/Co(II)- mof，它们由二十面体和四面体笼组成，具有新的（3,8）连接的三维拓扑结构。此外，稳定的Ni-MOF由于其暴露的氮活性位点，表现出良好的CO2/ ch4和CO2/ n2选择性吸附。
Two isostructural nanocage-based porous Ni/Co(II)-MOFs have been hydrothermally synthesized, which were interestingly composed of icosahedron and tetrahedron cages with a new (3,8)-connected 3D topology. Moreover, the stable Ni-MOF exhibits good selective CO2/CH4and CO2/N2adsorption owing to its exposed nitrogen active sites.