Recent Advances in the Development of Methods for the Preparation of Functionalized Azulenes for Electrochromic Applications
Recent Advances in the Development of Methods for the Preparation of Functionalized Azulenes for Electrochromic Applications
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DOI：
10.1002/chin.201202248
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发表时间：
2011-10
期刊：
影响因子：
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通讯作者：
S. Ito;Taku Shoji;N. Morita
中科院分区：
文献类型：
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作者：
S. Ito;Taku Shoji;N. Morita
介绍了近年来过渡金属催化反应和奥亲电杂芳基化反应制备芳基和杂芳基奥的研究进展。重点介绍了一类新颖的奥基取代金属试剂的开发。利用这些过程作为关键步骤的合成路线提供了直接获得具有独特氧化还原性质的官能化的基于甘菊环的先进材料的途径。
Recent advances made in the preparation of aryl-and heteroarylazulenes using transition-metal-catalyzed reactions and azulene electrophilic heteroarylation reactions are described. Emphasis is given to the development of novel azulenyl-substituted metallic reagents. The synthetic routes that utilize these processes as key steps provide straightforward access to functionalized azulene-based advanced materials that possess unique redox properties.