A versatile ruthenium precursor for biphasic catalysis and its application in ionic liquid biphasic transfer hydrogenation: conventional vs task-specific catalysts.
A versatile ruthenium precursor for biphasic catalysis and its application in ionic liquid biphasic transfer hydrogenation: conventional vs task-specific catalysts.
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DOI：
10.1021/ja048886k
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发表时间：
2004-06
影响因子：
15
通讯作者：
T. J. Geldbach;P. Dyson
中科院分区：
文献类型：
--
作者：
T. J. Geldbach;P. Dyson
据报道，合成了一种新型咪唑鎓标记的钌配合物，该配合物代表了水性和离子液体双相催化的多功能前体。其实用性在苯乙酮的高度对映选择性离子液体双相转移氢化中得到证明，并与传统（未标记）配合物进行了比较。
The synthesis of a novel imidazolium-tagged ruthenium complex, which represents a versatile precursor for aqueous and ionic liquid biphasic catalysis, is reported. Its utility is demonstrated in the highly enantioselective ionic liquid biphasic transfer hydrogenation of acetophenone and is compared to conventional (untagged) complexes.