A mechanochemically synthesised solid solution enables engineering of the sorption properties of a Werner clathrate

A mechanochemically synthesised solid solution enables engineering of the sorption properties of a Werner clathrate
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机械化学合成的固体溶液可实现维尔纳凝块吸附特性的工程设计

DOI:
10.1039/c2cc37261d
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发表时间:
2012-01-01
影响因子:
4.9
通讯作者:
Barbour, Leonard J.
Barbour, Leonard J.
中科院分区:
化学2区
文献类型:
--
作者:
Batisai, Eustina;Lusi, Matteo;Barbour, Leonard J.

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机械化学合成已被用来获得两种维尔纳配合物及其固溶体,这是传统“湿”化学无法获得的;值得注意的是,尽管结构和化学相似,但固溶体表现出与纯化合物不同的吸附特性。
Mechanochemical synthesis has been used to obtain two Werner complexes and their solid solution that could not be obtained by conventional "wet'' chemistry; remarkably, despite the structural and chemical similarity, the solid solution exhibits sorption properties that differ from those of the pure compounds.