An insight into the protonation property of a diiron azadithiolate complex pertinent to the active site of Fe-only hydirogenases
An insight into the protonation property of a diiron azadithiolate complex pertinent to the active site of Fe-only hydirogenases
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DOI：
10.1039/b513270c
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发表时间：
2006-01-21
影响因子：
4.9
通讯作者：
Sun, LC
中科院分区：
文献类型：
--
作者：
Dong, WB;Wang, M;Sun, LC
[{(mu-SCH2)(2)N(C6H4-p-NO2)}{Fe(CO)(2)(PMe3)}(2)]在4当量存在下的质子化。得到了两种化合物，一种是结晶学上表征了分子结构的钼氢二铁络合物，另一种是在吡啶存在下容易去质子化的p-S质子化物种。
Protonation of [{(mu-SCH2)(2)N(C6H4-p-NO2)}{Fe(CO)(2)(PMe3)}(2)] in the presence of 4 equiv. of HOTf afforded two species, a mu-hydride diiron complex, the molecular structure of which was crystallographically characterized, and a p-S-protonated species, which was readily deprotonated in the presence of pyridine.