One-Electron Oxidized Copper(II) Salophen Complexes: Phenoxyl versus Diiminobenzene Radical Species
One-Electron Oxidized Copper(II) Salophen Complexes: Phenoxyl versus Diiminobenzene Radical Species
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DOI：
10.1002/chem.201102882
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发表时间：
2012-01-01
影响因子：
4.3
通讯作者：
Thomas, Fabrice
中科院分区：
文献类型：
--
作者：
Kochem, Amelie;Jarjayes, Olivier;Thomas, Fabrice
二亚氨基苯桥的π-体系为prophenoxyl铜（II）salophen络合物增加了一个假定的氧化位点。结果表明，桥是有效的氧化还原活性和自由基的网站（苯氧基与二亚胺苯桥）在上述阳离子是通过选择性甲氧基取代（见图）。
Where is the radical The π-system of the diiminobenzene bridge adds a putative oxidation site to prophenoxyl copper (II) salophen complexes. It is shown that the bridge is effectively redox active and that the radical site (phenoxyl vs. diiminobenzene bridge) in the above cations is tuned by selective methoxy substitution (see figure).