Sedimentation in concentrated polystyrene solutions and the observation of an “anomaly” in a good solvent

Sedimentation in concentrated polystyrene solutions and the observation of an “anomaly” in a good solvent
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浓聚苯乙烯溶液中的沉淀以及良溶剂中“异常”的观察

DOI:
10.1016/0014-3057(77)90203-8
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发表时间:
1977
影响因子:
6
通讯作者:
L. Sundelöf
L. Sundelöf
中科院分区:
化学2区
文献类型:
--
作者:
B. Nyström;B. Porsch;L. Sundelöf

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Sedimentation coefficients are reported for three polystyrene fractions (molecular weights 1.1 × 105, 3.9 × 105and 1.8 × 106) in toluene andtrans-decalin (θ-conditions) up to high concentrations. The difference between the sedimentation behaviour in good and poor solvents is discussed; an “anomalous” effect was observed in toluene in a concentration region where incipient entanglement is likely.