Palladium-Catalyzed Ring-Opening Thiocarbonylation of Vinylcyclopropanes with Thiols and Carbon Monoxide
Palladium-Catalyzed Ring-Opening Thiocarbonylation of Vinylcyclopropanes with Thiols and Carbon Monoxide
复制标题
钯催化乙烯基环丙烷与硫醇和一氧化碳的开环硫代羰基化反应
DOI：
10.1021/jo801725j
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发表时间：
2009-01-16
影响因子：
3.6
通讯作者：
Alper, Howard
中科院分区：
文献类型：
--
作者：
Li, Chang-Feng;Xiao, Wen-Jin;Alper, Howard
钯催化的乙烯基环丙烷与硫醇和一氧化碳的开环硫代羰基化反应以中等至优异的产率得到相应的不饱和硫酯。该反应为VCP的开环硫代羰基化提供了一种通用方法。它进一步证明了过渡金属催化剂用于合成有机硫化合物的实用性。
Palladium-catalyzed ring-opening thiocarbonylation of vinylcyclopropanes (VCPs) with thiols and carbon monoxide affords the corresponding unsaturated thioesters in moderate to excellent yields. This reaction provides a general method for the ring-opening thiocarbonylation of VCPs. It further demonstrates the utility of transition metal catalysts for the synthesis of organosulfur compounds.