AUTOXIDATION OF PYROGALLOL - GENERAL CHARACTERISTICS AND INHIBITION BY CATALASE
AUTOXIDATION OF PYROGALLOL - GENERAL CHARACTERISTICS AND INHIBITION BY CATALASE
复制标题
DOI：
10.1038/1811153a0
复制
发表时间：
1958-01-01
期刊：
影响因子：
64.8
通讯作者：
SIEGEL, BZ
中科院分区：
文献类型：
--
作者：
SIEGEL, SM;SIEGEL, BZ
在研究酚类的氧化聚合过程中，酚类单体的实验包括对焦性没食子酸的空气氧化的观察。焦性没食子酸氧化的最终产物被认为是羟基化苯并环酚酮，purpurogallin 2，其特征在于两个紫外吸收最大值，270-275 mµ和310-320 mµ。在425 mµ的范围内有一个可见的最大值。我们已经发现，purpurogallin既不是唯一的，也不是连苯三酚氧化的终端产品，它不是在均匀系统中的缓慢氧化过程中形成。本帐户介绍了一些特点的焦性没食子酸自氧化反应的反应性质，以及其生物学意义，并构成部分，目前正在进行的工作的基础上表面定向聚合的焦性没食子酸。
DURING a study of the oxidative polymerization of phenols1, experiments with phenolic monomers included observations on the air oxidation of pyrogallol. The end-product of pyrogallol oxidation is accepted to be the hydroxylated benztropolone, purpurogallin2, which is characterized by two ultraviolet absorption maxima, 270–275 mµ and 310–320 mµ. and a visible maximum in the region of 425 mµ. We have found that purpurogallin is neither the sole nor the terminal product of pyrogallol oxidation, and it is not formed during slow oxidation in homogeneous systems. The present account describes some features of pyrogallol autoxidation reflecting upon the nature of the reaction, and on its biological significance as well, and constitutes in part, a basis for work now in progress on surface-directed polymerization of pyrogallol.