Recent Advances in the Development of Molecular Catalyst-Based Anodes for Water Oxidation toward Artificial Photosynthesis.
Recent Advances in the Development of Molecular Catalyst-Based Anodes for Water Oxidation toward Artificial Photosynthesis.
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DOI：
10.1002/cssc.201802795
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发表时间：
2019-05
期刊：
影响因子：
8.4
通讯作者：
Zaki N. Zahran;Yuta Tsubonouchi;E. Mohamed;M. Yagi
中科院分区：
文献类型：
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作者：
Zaki N. Zahran;Yuta Tsubonouchi;E. Mohamed;M. Yagi
催化水氧化是开发将太阳能作为可再生燃料储存的人工光合系统的瓶颈。在过去的二十年中，已经报道了各种分子水氧化催化剂（WOC）。鉴于其在人工光合作用装置中的应用，将分子催化剂涂覆到导电/半导电载体表面以制备高效且稳定的水氧化阳极/光阳极是必要的。基于分子WOC的阳极对于开发光伏人工光合作用装置是必不可少的，而且，分子WOC在阳极上的性能将为设计用于光电化学（PEC）水氧化的扩展的基于分子WOC的光阳极提供重要的见解。本文综述了近二十年来分子WOC基阳极的研究进展，并展望了这种阳极在人工光合作用中的应用前景。
Catalytic water oxidation represents a bottleneck for developing artificial photosynthetic systems that store solar energy as renewable fuels. A variety of molecular water oxidation catalysts (WOCs) have been reported over the last two decades. In view of their applications in artificial photosynthesis devices, it is essential to immobilize molecular catalysts onto the surfaces of conducting/semiconducting supports for fabricating efficient and stable water oxidation anodes/photoanodes. Molecular WOC-based anodes are essential for developing photovoltaic artificial photosynthesis devices and, moreover, the performance of molecular WOC on anodes will provide important insight into designing extended molecular WOC-based photoanodes for photoelectrochemical (PEC) water oxidation. This Review concerns recent progress in the development of molecular WOC-based anodes over the last two decades and looks at the prospects for using such anodes in artificial photosynthesis.