ELECTRONIC-PROPERTIES OF THE LINEAR ANTIFERROMAGNETICALLY COUPLED CLUSTERS [FE3S4(SR)4]3-, STRUCTURAL ISOMERS OF THE [FE3S4]+ UNIT IN IRON SULFUR PROTEINS
ELECTRONIC-PROPERTIES OF THE LINEAR ANTIFERROMAGNETICALLY COUPLED CLUSTERS [FE3S4(SR)4]3-, STRUCTURAL ISOMERS OF THE [FE3S4]+ UNIT IN IRON SULFUR PROTEINS
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DOI：
10.1021/ja00332a031
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发表时间：
1984-01-01
影响因子：
15
通讯作者：
HOLM, RH
中科院分区：
文献类型：
--
作者：
GIRERD, JJ;PAPAEFTHYMIOU, GC;HOLM, RH
为了表征这一独特的磁性体系，研究了三核簇合物[Fe_3S_4(SR)_4]_3-(R=Et，Ph)的磁化率、磁化强度和Moessbauer谱性质，该簇合物含有线形的[Fe(Mu2-S)2Fe(Mu2-S)2Fe]+核，Fe的分离度为2.71 nm。
The magnetic susceptibility, magnetization and Moessbauer spectroscopic properties of the trinuclear clusters [Fe3S4(SR)4]3- (R = Et, Ph), containing the linear [Fe(.mu.2-S)2Fe(.mu.2-S)2Fe]+ core with Fe.cntdot..cntdot..cntdot.Fe separations of 2.71 .ANG., were examined in order to characterize this unique magnetic system.