Estimation of the Rh-Rh bond dissociation energy in the (octaethylporphyrinato)rhodium(II) dimer by proton NMR line broadening
Estimation of the Rh-Rh bond dissociation energy in the (octaethylporphyrinato)rhodium(II) dimer by proton NMR line broadening
复制标题
通过质子 NMR 谱线展宽估算 (八乙基卟啉)铑 (II) 二聚体中的 Rh-Rh 键解离能
DOI：
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发表时间：
1988
期刊：
影响因子：
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通讯作者：
M. D. Farnos
中科院分区：
文献类型：
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作者：
B. Wayland;Virginia L. Coffin;M. D. Farnos
八乙基卟啉二聚体（（OEP）Rh）/sub 2/已被报道具有令人感兴趣的有机金属反应性范围。本文报道了从/sup 1/H NMR谱线增宽研究中估计二聚体中的Rh-Rh键离解能（BDE）。这一离解能值已用于推导（OEP）Rh-H中的（R-H）BDE和（OEP）Rh-CHO中的（Rh-C）BDE。参考文献19篇，附图2幅。
The octaethylporphyrin dimer ((OEP)Rh)/sub 2/ has been reported to have an interesting range of organometallic reactivity. An estimation of the Rh-Rh bond dissociation energy (BDE) in the dimer from /sup 1/H NMR line broadening studies is reported herein. This value for the dissociation energy has been used in deriving the (R-H)BDE in (OEP)Rh-H and the (Rh-C)BDE in (OEP)Rh-CHO. 19 references, 2 figures.