Dynamics and phase transitions in spin-crossover complexes: detailed nature of phase transitions in the solvate series bis(3-ethoxysalicylideneaziridinopropylaminato)iron perchlorate.solvate
Dynamics and phase transitions in spin-crossover complexes: detailed nature of phase transitions in the solvate series bis(3-ethoxysalicylideneaziridinopropylaminato)iron perchlorate.solvate
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自旋交叉配合物中的动力学和相变：溶剂化物系列双(3-乙氧基水杨烯氮丙啶基丙基氨基)高氯酸铁.溶剂化物中相变的详细性质
DOI：
10.1021/ic00064a018
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发表时间：
1993
影响因子：
4.6
通讯作者：
D. Hendrickson
中科院分区：
文献类型：
--
作者：
A. Conti;K. Kaji;Yatsuhisa Nagano;Kathryn M. Sena;Y. Yumoto;R. Chadha;A. Rheingold;M. Sorai;D. Hendrickson
研究了[Fe（3-OEt-SalAPA）2 ]-（ClO 4）-S（S为C6 H6，C6 H6，C6 H6，C6 H5 Cl，C6 H5 Br或o-C6 H4 Cl 2）系列的自旋交叉现象和相变的详细性质.采用了前一篇文章的数据库，晶体堆积分析，C6 D 6，C6 D5 Cl和C6 D5 Br溶剂化物的变温固态2 HNMR数据，以及13-300 K的绝热量热数据
The detailed nature of the spin-crossover phenomenon and phase transitions observed for the [Fe(3-OEt-SalAPA) 2 ]-(ClO 4 )-S (S is C 6 H 6 , C 6 H 6 , C 6 H 6 , C 6 H 5 Cl, C 6 H 5 Br or o-C 6 H 4 Cl 2 ) series is examined. The data base from the preceding paper together with an analysis of the crystal packing, variable-temperature solid-state 2 H NMR data for C 6 D 6 , C 6 D 5 Cl and C 6 D 5 Br solvates, and 13-300 K adiabatic calorimetry data are employed