Vapor-liquid equilibria of nonideal solutions - Utilization of theoretical methods to extend data

Vapor-liquid equilibria of nonideal solutions - Utilization of theoretical methods to extend data
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DOI:
10.1021/ie50389a013
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发表时间:
1942-01-01
影响因子:
--
通讯作者:
Colburn, AP
Colburn, AP
中科院分区:
其他
文献类型:
--
作者:
Carlson, HC;Colburn, AP

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当汽液平衡数据用活度系数计算时,可以很容易地加以评价和推广。由货车Lear、Margules和Scatchard和Hamer提出的二元混合物的活度系数与液相组成和经验常数的关系式能够拟合大多数现有的汽液平衡数据。
Vapor-liquid equilibrium data may be readily evaluated and extended when they are calculated ai activity coefficients. The equations proposed by van Lear, Margules, and Scatchard and Hamer, which express the activity coefficients of both components of a binary mixture as functions of the liquid composition and empirical con-stants, are capable of fitting most of the available vapor-liquid equilibrium data.