Nanoscale spherical architectures fabricated by metal coordination of multiple dipyrrin moieties
Nanoscale spherical architectures fabricated by metal coordination of multiple dipyrrin moieties
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DOI：
10.1021/ja0637301
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发表时间：
2006-08-09
影响因子：
15
通讯作者：
Nakanishi, Takashi
中科院分区：
文献类型：
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作者：
Maeda, Hiromitsu;Hasegawa, Masahiro;Nakanishi, Takashi
苯乙炔桥联的二吡咯“二聚体”进行了锌II络合得到的配位聚合物，它提供了荧光胶体球形物体在溶液中，以及根据间隔单元在基板上。使用THF和水的混合物，观察到独特的形态，如钟形和“高尔夫球”样结构。
Phenylethynyl-bridged dipyrrin “dimers” have performed ZnIIcomplexation to give coordination polymers, which provided the fluorescent colloidal spherical objects in solution as well as on the substrate according to the spacer units. Using a mixture of THF and water, unique morphologies, such as bell-shaped and “golf ball”-like architectures, were observed.