Reversible water-induced magnetic and structural conversion of a flexible microporous Ni(II)Fe(III) ferromagnet.
Reversible water-induced magnetic and structural conversion of a flexible microporous Ni(II)Fe(III) ferromagnet.
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DOI：
10.1021/ja069166b
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发表时间：
2007-03
影响因子：
15
通讯作者：
N. Yanai;Wakako Kaneko;Ko Yoneda;M. Ohba;S. Kitagawa
中科院分区：
文献类型：
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作者：
N. Yanai;Wakako Kaneko;Ko Yoneda;M. Ohba;S. Kitagawa
氰化物桥联的铁磁体[Ni（dipn）]2[Ni（dipn）（H2O）][Fe（CN）6]2·11 H2O（dipn = N，N-二（3-氨基丙基）胺）具有三维微孔结构，表现出可逆的铁磁体/顺磁体转变，并伴随着气态水诱导的类晶体-非晶相变
A cyanide-bridged bimetallic ferromagnet, [Ni(dipn)]2[Ni(dipn)(H2O)][Fe(CN)6]2·11H2O (dipn = N,N-di(3-aminopropyl)amine) providing a 3-D microporous framework, shows reversible ferromagnet/paramagnet conversion associated with a gaseous water-induced crystal-to-amorphous-like phase transformation