Infra-red spectra of phthalocyanine and naphthalocyanine in sandwich-type (na)phthalocyaninato and porphyrinato rare earth complexes

Infra-red spectra of phthalocyanine and naphthalocyanine in sandwich-type (na)phthalocyaninato and porphyrinato rare earth complexes
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DOI:
10.1016/s0277-5387(99)00097-2
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发表时间:
1999-06
期刊:
影响因子:
2.6
通讯作者:
Jianzhuang Jiang;D. Arnold;Hui Yu
Jianzhuang Jiang;D. Arnold;Hui Yu
中科院分区:
化学3区
文献类型:
--
作者:
Jianzhuang Jiang;D. Arnold;Hui Yu

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收集并系统研究了一系列88种夹心型(na)酞菁和卟啉稀土配合物,包括杂配双层和三层稀土配合物的红外光谱数据。因此,比较描述了未取代和取代的(na)酞菁单自由基阴离子Pc'⋅-(Pc'=Pc, Pc*)、Nc'⋅-(Nc'=Nc, Nc*)和双阴离子Pc'2-(Pc'=Pc, Pc*)的IR特性。
The infra-red spectroscopic data for a series of 88 sandwich-type (na)phthalocyaninato and porphyrinato rare earth complexes, including heteroleptic double- and triple-deckers, have been collected and systematically studied. The IR characteristics for unsubstituted and substituted (na)phthalocyaninato monoradical anion Pc′⋅−(Pc′=Pc, Pc*), Nc′⋅−(Nc′=Nc, Nc*), and dianion Pc′2−(Pc′=Pc, Pc*) are thus comparatively described.