Influences of Si addition on the thermal stability and crystallization behavior of Al-Y binary amorphous alloys

Influences of Si addition on the thermal stability and crystallization behavior of Al-Y binary amorphous alloys
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Si添加对Al-Y二元非晶合金热稳定性和结晶行为的影响

DOI:
10.1016/j.jallcom.2021.159816
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发表时间:
2021-08
影响因子:
6.2
通讯作者:
Li J. F.
Li J. F.
中科院分区:
材料科学2区
文献类型:
--
作者:
Li W.;Yang L.;Zhang Y. G.;Kong L. T.;Li J. F.

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采用差示扫描量热法、X射线衍射和透射电子显微镜对(Al 90 Y10)100−xSix(x= 0、1、2、2.5和3at%)非晶合金的晶化行为进行了表征。在Al 90 Y 10基非晶合金中加入Si,使α-Al的初晶化提前到较低温度,抑制了残余非晶相中Al 4 Y的析出,但促进了Al 3 Y的晶化。Si的加入显著稳定了α-Al 3 Y相,使(Al 90 Y10)98 Si 2合金的铸态和完全晶化带均由α-Al和α-Al 3 Y组成,而Al 90 Y10合金中相应的产物为α-Al和β-Al 3 Y。2.5at%Si的加入使α-Al晶化分为两个阶段,两个峰之间的温度间隔为140 K。其原因可能与Si的加入使非晶合金中Y原子的浓度波动增大和晶化过程中Y原子扩散减慢有关。
In the present study, the crystallization behavior of (Al90Y10)100−xSix(x= 0, 1, 2, 2.5 and 3 at%) amorphous alloys were characterized by differential scanning calorimetry, X-ray diffraction and transmission electron microscopy. As Si is added to the Al90Y10base amorphous alloy, the primary crystallization of α-Al is advanced to lower temperature, the precipitation of Al4Y in the residual amorphous phase is depressed but the crystallization of Al3Y is promoted. The Si addition stabilizes the α-Al3Y phase significantly, due to which both the as-cast ingot and the fully crystallized ribbon of (Al90Y10)98Si2alloy consist of α-Al and α-Al3Y, whereas the corresponding products in Al90Y10alloy are α-Al and β-Al3Y. The addition of 2.5 at% Si makes the crystallization of α-Al split into two stages with a temperature interval of 140 K between the two peaks. The reason is thought to be related with the enhanced concentration fluctuation in amorphous alloy and the slower diffusion of Y atoms in crystallization after the Si addition.
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