Structure and ion transport behavior analysis of ionic liquid analogues based on magnesium chloride

Structure and ion transport behavior analysis of ionic liquid analogues based on magnesium chloride
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基于氯化镁的离子液体类似物的结构和离子传输行为分析

DOI:
10.1016/j.molliq.2010.11.005
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发表时间:
2011-01
影响因子:
6
通讯作者:
Jia, Yongzhong
Jia, Yongzhong
中科院分区:
化学2区
文献类型:
--
作者:
Yue, Duyuan;Jing, Yan;Sun, Jinhe;Wang, Xiaohua;Jia, Yongzhong

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报道了一种基于氯化镁和氯化胆碱的均匀无色离子液体类似物。用红外光谱对离子液体类似物的结构进行了初步研究。确定了主要的化学基团,分析了不同化学基团之间的相互作用。热分析表明,离子液体类似物在室温至120℃范围内是稳定的。测量了离子液体类似物的粘度、表面张力和电导率等物理性质随温度和成分的变化。利用空穴理论分析了离子输运行为。结果表明,离子液体类似物的电导率受离子迁移率和合适空隙的控制。
A homogeneous, colorless ionic liquid analogue based on magnesium chloride and choline chloride is reported. The structure of the ionic liquid analogues is preliminarily investigated by FTIR. The main chemical groups are confirmed and the interactions between different chemical groups are analyzed. Thermal analysis shows that the ionic liquid analogue is stable from room temperature to 120°C. The physical properties of the ionic liquid analogues such as viscosity, surface tension and conductivity are measured as function of temperature and compositions. The ion transport behaviors are analyzed using hole-theory. It is shown that the conductivity of the ionic liquid analogues is controlled by the ion mobility and the suitable voids.
DOI: 10.1039/ft9908601453
发表时间: 1990-05-07
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