Chemical Science of π-Electron Systems
Chemical Science of π-Electron Systems
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DOI：
10.1007/978-4-431-55357-1
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发表时间：
2015
期刊：
影响因子：
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通讯作者：
T. Akasaka;A. Osuka;S. Fukuzumi;H. Kandori;Y. Aso
中科院分区：
文献类型：
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作者：
T. Akasaka;A. Osuka;S. Fukuzumi;H. Kandori;Y. Aso
以富勒烯和卟啉为代表的电子基分子的多功能性和广泛的潜力不断提供独特的，有时是意想不到的性质和功能，并不断被发现和应用于功能器件中。为了促进对具有更复杂和复杂的秩序和功能的高度精致空间的研究，日本文部科学省（MEXT）启动了一项名为“高度精致空间的出现及其功能”的研究项目，作为创新领域科学研究资助项目（2008-2012）。在这个联合项目中，高度精细的空间被定义为源于电子相互作用的高度复杂的秩序/系统。前沿研究基于明确定义的战略目标，以及来自创新和意外发现的新兴方法。研究项目分为四组（A01-04）。由Takeshi Akasaka教授领导的A01研究小组构建了包括金属-endofullerenes在内的非平面性新电子系统，而由Atsuhiro Osuka教授领导的A02研究小组通过电子基分子的组装开发了高度精细的空间功能。在Shunichi Fukuzumi教授领导的A03研究小组中，基于新型的基于电子的分子和组件，通过阐明高度精细空间的电子、光学和磁相互作用，探索了革命性的功能。由Hideki Kandori教授领导的A04研究小组研究了生物分子与高度精细空间之间的相互作用，发现了生物学的新现象，创造了生物学的新概念。这本书由八个部分组成。第一部分：平面电子系统的扩展，第二部分：弯曲电子系统，第三部分：卟啉类化合物，第四部分：开壳电子系统，第五部分：杂原子共轭电子系统，第六部分：电子系统的超分子化学，第七部分：电子系统的创新功能，第八部分：生物系统和仿生学中的电子系统。它总结了v . next项目的前沿研究
The versatility and wide potential of-electron-based molecules, as typified by fullerenes and porphyrins, have continued to provide unique and sometimes unexpected properties and functions being continuously discovered and utilized in functional devices. In order to facilitate the investigation on highly elaboratedspaces with more sophisticated and complex orders and functionality, a research project entitled “Emergence of Highly Elaborated-Space and Its Function” has been launched as a Grant-in-Aid for Scientific Research on Innovative Areas (2008–2012) by The Ministry of Education, Culture, Sports, Science and Technology of Japan (MEXT). In this joint project, highly elaborated-spaces are defined as highly complex orders/systems that stem from the-electron-based interactions. Cutting-edge research has been performed based on clearly defined strategic objectives as well as an emergent approach that comes from innovation of unpredicted discovery. The research project consists of four groups (A01–04). The research group A01 led by Prof. Takeshi Akasaka has constructed novel-electron systems of nonplanarity including metal-endofullerenes, whereas the research group A02 led by Prof. Atsuhiro Osuka has developed highly elaborated-space functionality through the assembly of-electron-based molecules. Based on new types ofelectron-based molecules and assemblies, the revolutionary functions have been explored by clarifying the electronic, optical, and magnetic interactions of the highly elaborated-spaces in research group A03 led by Prof. Shunichi Fukuzumi. Research group A04 led by Prof. Hideki Kandori has studied the interactions between biological molecules with highly elaborated-space to discover new phenomena and create new concepts in biology. This book is composed of eight parts. Part I: Extension of Planar-Electron Systems, Part II: Curved-Electron Systems, Part III: Porphyrinoids, Part IV: Open-Shell-Electron Systems, Part V: Heteroatom-Conjugated-Electron Systems, Part VI: Supramolecular Chemistry of-Electron systems, Part VII: Innovative Function of-Electron Systems, and Part VIII:-Electron Systems in Biosystems and Biomimetics. It summarizes cutting-edge research in the MEXT project of v