Alkaline-Earth-Promoted CO Homologation and Reductive Catalysis.
Alkaline-Earth-Promoted CO Homologation and Reductive Catalysis.
复制标题
DOI：
10.1002/anie.201505851
复制
发表时间：
2015-08-17
期刊：
影响因子：
--
通讯作者：
Mahon MF
中科院分区：
文献类型：
--
作者：
Anker MD;Hill MS;Lowe JP;Mahon MF
Reaction between a β-diketiminato magnesium hydride and carbon monoxide results in the isolation of a dimeric cis-enediolate species through the reductive coupling of two CO molecules. Under catalytic conditions with PhSiH3, an observable magnesium formyl species may be intercepted for the mild reductive cleavage of the CO triple bond.
