Synthesis of small palladium nanoparticles stabilized by bisphosphine BINAP bearing an alkyl chain and their palladium nanoparticle-catalyzed carbon-carbon coupling reactions under room-temperature.
Synthesis of small palladium nanoparticles stabilized by bisphosphine BINAP bearing an alkyl chain and their palladium nanoparticle-catalyzed carbon-carbon coupling reactions under room-temperature.
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DOI：
10.1039/b605390b
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发表时间：
2006-08
影响因子：
4.9
通讯作者：
Ryouta Tatumi;T. Akita;H. Fujihara
中科院分区：
文献类型：
--
作者：
Ryouta Tatumi;T. Akita;H. Fujihara
制备了新型双膦配体C8-BINAP和C8-BINAP稳定的钯纳米颗粒； C8-BINAP被发现是一种有效的保护配体，用于制备和稳定具有非常小核尺寸和窄尺寸分布的钯纳米颗粒，并且C8-BINAP-Pd纳米颗粒在室温下可作为碳-碳偶联反应的有效催化剂。
A new bisphosphine ligand, C8-BINAP, and C8-BINAP-stabilized palladium nanoparticles have been prepared; C8-BINAP was found to be an effective protecting ligand for preparing and stabilizing palladium nanoparticles with very small core size and narrow size distribution and the C8-BINAP-Pd nanoparticles behave as an efficient catalyst for carbon-carbon coupling reactions at room temperature.