AXIAL VS EQUATORIAL BONDING IN TRIGONAL-BIPYRAMIDAL COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURE OF [BIS(TRIPHENYLPHOSPHINE)IMMINIUM]TETRACARBONYLCYANOIRON(O), [(C6H5)3P)2N][FE(CO)4CN]
AXIAL VS EQUATORIAL BONDING IN TRIGONAL-BIPYRAMIDAL COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURE OF [BIS(TRIPHENYLPHOSPHINE)IMMINIUM]TETRACARBONYLCYANOIRON(O), [(C6H5)3P)2N][FE(CO)4CN]
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DOI：
10.1021/ic50134a002
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发表时间：
1974-01-01
影响因子：
4.6
通讯作者：
RAYMOND, KN
中科院分区：
文献类型：
--
作者：
GOLDFIELD, SA;RAYMOND, KN
引言虽然五配位络合物的立体化学不稳定性是出于几个原因的兴趣，我们的兴趣仍然集中在使用这些络合物的几何形状的变化的键合的高灵敏度。随着单个配体的改变，一系列络合物的结构发生变化，从而可以系统地研究成键的各种组分。我们已经使用这种技术以前在研究的相对重要性的金属d-电子配置在确定一个复杂的几何形状。2，3通常，
Introduction Although the stereochemical lability of five-coordinate complexes is of interest for several reasons, our interest has remained focused on the use of the high sensitivity of the geometry of these complexes to changes in the bonding. The change in structure of a series of complexes as individual ligands are changed allows a systematic investigation of the various components of the bonding. We have used this technique previously in studying the relative importance of the metal d-electron configuration in determining the geometry of a complex. 2, 3 Often the difference in energy between