The heteronuclear bonding between heavier Group 14 elements and transition metals: a novel trioxystannate-iron complex with an unusual stannate fragment.
The heteronuclear bonding between heavier Group 14 elements and transition metals: a novel trioxystannate-iron complex with an unusual stannate fragment.
复制标题
较重的 14 族元素和过渡金属之间的异核键合：一种具有不寻常锡酸盐片段的新型三氧基锡酸盐-铁络合物。
DOI：
10.1039/b717197h
复制
发表时间：
2008
影响因子：
4
通讯作者：
S. Bukalov
中科院分区：
文献类型：
--
作者：
V. Khrustalev;O. Chernov;R. Aysin;Ivan A. Portnyagin;M. Nechaev;S. Bukalov
合成了一种新的三氧锡酸盐-过渡金属配合物{[Li][(Me(2)NCH(2)CH(2)O)(3)Sn-Fe(CO)(4)]}(2)(3)，在溶液中表现出一种较重的14族元素与过渡金属之间的异核键，并用核磁共振、拉曼和红外光谱以及固体中的拉曼光谱和x射线衍射分析对其进行了完整的表征。
A new trioxystannate-transition metal complex, {[Li][(Me(2)NCH(2)CH(2)O)(3)Sn-Fe(CO)(4)]}(2) (3), exhibiting an unusual type of the heteronuclear bonding between heavier Group 14 elements and transition metals, has been synthesised and completely characterised by NMR, Raman and IR spectroscopy in solution as well as by Raman spectroscopy and X-ray diffraction analysis in the solid state.