Low-temperature heat capacity and thermodynamic functions of GaTe

Low-temperature heat capacity and thermodynamic functions of GaTe
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GaTe的低温热容和热力学函数

DOI:
10.1134/s0020168506080097
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发表时间:
2006
影响因子:
0.8
通讯作者:
N. N. Smirnova
N. N. Smirnova
中科院分区:
材料科学4区
文献类型:
--
作者:
A. Tyurin;K. Gavrichev;V. Zlomanov;N. N. Smirnova

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使用绝热量热法测量了GaTe的热容量,范围为6.8至337.95 K。计算结果被用来计算的热容,熵,焓增量,在10-320 K的温度范围内,在标准条件下的GaTe的约化吉布斯自由能。298.15K时,GaTe的热力学性质为Cp 0(298.15 K)= 48.96 ± 0.10 J/(K mol),S0(298.15 K)= 81.30 ± 0.16 J/(K mol),H0(298.15 K)−H0(0 K)= 10.84 ± 0.02 kJ/mol,Φ0(298.15 K)= 44.95 ± 0.09 J/(K mol)。
The heat capacity of GaTe is measured from 6.8 to 337.95 K using adiabatic calorimetry. The results are used to calculate the heat capacity, entropy, enthalpy increment, and reduced Gibbs energy of GaTe in the temperature range 10–320 K under standard conditions. The 298.15-K thermodynamic properties of GaTe areCp0(298.15 K) = 48.96 ± 0.10 J/(K mol),S0(298.15 K) = 81.30 ± 0.16 J/(K mol),H0(298.15 K) −H0(0 K) = 10.84 ± 0.02 kJ/mol, and Φ0(298.15 K) = 44.95 ± 0.09 J/(K mol).