Geometric effect of Ru/HSAG@mSiO2: a catalyst for selective hydrogenation of cinnamaldehyde
Geometric effect of Ru/HSAG@mSiO2: a catalyst for selective hydrogenation of cinnamaldehyde
复制标题
DOI：
10.1039/c4ra04811c
复制
发表时间：
2014-07
期刊：
影响因子：
3.9
通讯作者：
Hangjia Shen;Haodong Tang;Haiyu Yan;W. Han;Ying Li;J. Ni
中科院分区：
文献类型：
--
作者：
Hangjia Shen;Haodong Tang;Haiyu Yan;W. Han;Ying Li;J. Ni
A new strategy to synthesize a catalyst consisting of graphite-supported Ru nanoparticles encapsulated by mesoporous silica layers was developed via a facile and scalable wet-chemical process. The intended structures were confirmed with N2 sorption, CO chemisorption, TEM and SEM. The geometric effect of the pores in the silica layer of Ru/HSAG@mSiO2 was evaluated in the hydrogenation of cinnamaldehyde and showed 15% higher selectivity to unsaturated alcohol and three times higher turnover frequency (TOF) relative to unconfined Ru/HSAG catalyst with the equivalent size of Ru particles.
