Synthetic methodology using tertiary phosphines as nucleophilic catalysts

Synthetic methodology using tertiary phosphines as nucleophilic catalysts
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DOI:
10.1351/pac200577121985
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发表时间:
2005-12-01
影响因子:
1.8
通讯作者:
Lu, C
Lu, C
中科院分区:
化学4区
文献类型:
--
作者:
Lu, XY;Du, YS;Lu, C

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Allenoates or 2-alkynoates are known to react with tertiary phosphines to form the phosphine-substituted 1,3-dipoles, which can react with various substrates with the simultaneous elimination of the tertiary phosphine. The reaction is catalytic to the tertiary phosphine used. The investigation of the appropriate dipolarophiles and the further extension of this reaction are discussed.