Methyltrioxorhenium catalysis in nonconventional solvents: a great catalyst in a safe reaction medium.
Methyltrioxorhenium catalysis in nonconventional solvents: a great catalyst in a safe reaction medium.
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非常规溶剂中的甲基三氧铼催化：安全反应介质中的出色催化剂。
DOI：
10.1002/cssc.201000022
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发表时间：
2010
期刊：
影响因子：
8.4
通讯作者：
F. De Angelis
中科院分区：
文献类型：
--
作者：
M. Crucianelli;R. Saladino;F. De Angelis
由于社会和政府要求保护环境和保护人类健康的压力，化学工艺可持续性的要求，反映在减少废物和使用安全试剂和反应条件上，变得更加严格。催化提供了与绿色化学相关的许多益处，包括降低能量反应要求;催化，而不是化学计量的材料量;增加选择性;降低加工和分离剂的消耗;以及在许多情况下，使用毒性较小的化合物。本课题组长期以来一直在研究甲基三氧化铼在不同底物的氧化功能化反应中的作用，主要是以H（2）O（2）或其尿素-过氧化氢络合物为主要氧化剂。在这篇综述论文中，我们的目的是提供一个完整的文献帐户的催化活性和选择性的甲基trioxorhenium在氧化官能化反应，无论是在非常规溶剂或无溶剂条件下，特别强调使用离子液体作为绿色反应介质。
The requirement that chemical processes are sustainable, reflected in waste reduction and the use of safe reagents and reaction conditions, is becoming even more stringent as a result of pressure by society and governments to preserve the environment and protect human health. Catalysis offers numerous benefits related to green chemistry, including lowered energetic reaction requirements; catalytic, rather than stoichiometric, amounts of materials; increased selectivity; lowered consumption of processing and separation agents; and, in many cases, the use of less-toxic compounds. Our research group has for a long time been studying methyltrioxorhenium in the oxyfunctionalization of different substrates, by using H(2)O(2) or its urea-hydrogen peroxide complex as the primary oxidant. In this Review paper we aim to provide a full literature account on the catalytic activity and selectivity of methyltrioxorhenium in the oxyfunctionalization reaction, either in nonconventional solvents or under solvent-free conditions, with a particular emphasis on the use of ionic liquids as green reaction media.
甲基三氧铼和 3-氰基吡啶催化的过氧化氢水溶液对烯烃的有效环氧化。
DOI：
10.1021/jo005623
发表时间：
2000
期刊：
The Journal of organic chemistry
影响因子：
--
作者：
Adolfsson,H;Copéret,C;Chiang,JP;Yudin,AK
通讯作者：
Yudin,AK