Microporous Polymers from a Carbazole-Based Triptycene Monomer: Synthesis and Their Applications for Gas Uptake.
Microporous Polymers from a Carbazole-Based Triptycene Monomer: Synthesis and Their Applications for Gas Uptake.
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DOI：
10.1002/asia.201501105
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发表时间：
2016
期刊：
影响因子：
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通讯作者：
Tian‐Long Zhai;Liang-Xiao Tan;Yi Luo;Jun‐Min Liu;B. Tan;X. Yang;Huibi Xu;Chun Zhang
中科院分区：
文献类型：
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作者：
Tian‐Long Zhai;Liang-Xiao Tan;Yi Luo;Jun‐Min Liu;B. Tan;X. Yang;Huibi Xu;Chun Zhang
以三卡巴酰基三泰烯（TCT）为单体，采用两种经济高效的合成策略制备了两种新型有机微孔聚合物TCP-A和TCP-B。通过FT-IR、固体（13）C NMR、粉末XRD、SEM、TEM和气体吸收测试对其结构和性能进行了表征。TCP-B具有较高的表面积(1469 m（2) g(-1)）、优异的储氢能力（1 bar/77 K时储氢量为1.70 wt %）和二氧化碳吸收能力（1 bar/273 K时储氢量为16.1 wt %），是一种具有潜在储气应用前景的材料。
Two kinds of novel organic microporous polymers TCPs (TCP-A and TCP-B) were prepared by two cost-effective synthetic strategies from the monomer of tricarbazolyltriptycene (TCT). Their structure and properties were characterized by FT-IR, solid (13) C NMR, powder XRD, SEM, TEM, and gas absorption measurements. TCP-B displayed a high surface area (1469 m(2) g(-1) ) and excellent H2 storage (1.70 wt % at 1 bar/77 K) and CO2 uptake abilities (16.1 wt % at 1 bar/273 K), which makes it a promising material for potential application in gas storage.