Controlled molecular orientation in an adlayer of a supramolecular assembly consisting of an open-cage C60 derivative and ZnII octaethylporphyrin on Au(111).

Controlled molecular orientation in an adlayer of a supramolecular assembly consisting of an open-cage C60 derivative and ZnII octaethylporphyrin on Au(111).
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DOI:
10.1002/anie.200453959
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发表时间:
2004-06
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通讯作者:
Soichiro Yoshimoto;E. Tsutsumi;Yosuke Honda;Y. Murata;M. Murata;K. Komatsu;O. Ito;K. Itaya
Soichiro Yoshimoto;E. Tsutsumi;Yosuke Honda;Y. Murata;M. Murata;K. Komatsu;O. Ito;K. Itaya
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文献类型:
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作者:
Soichiro Yoshimoto;E. Tsutsumi;Yosuke Honda;Y. Murata;M. Murata;K. Komatsu;O. Ito;K. Itaya

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图2.典型的大规模STM图像(30 - 30 nm 2),在0.85 V相对于RHE下获得,在0.05 MH 2SO 4中,1吸附层a)直接形成在Au(111)上和B)在[Zn(oep)]改性的Au(111)上。探针的电位为0.45 V,电流分别为0.5 nA和0.3 nA。
Figure 2. Typical large-scale STM images (30 30 nm2), acquired at 0.85 V versus RHE, of the 1 adlayer a) directly formed on Au (111) and b) on [Zn (oep)]-modified Au (111) in 0.05 MH2so4. The potential of the tip was 0.45 V. Tunneling currents were 0.5 nA and 0.3 nA, respectively.