Toward Vibrational Mode Control in Catalysis
Toward Vibrational Mode Control in Catalysis
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DOI：
10.1126/science.1090172
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发表时间：
2003-10
期刊：
影响因子：
56.9
通讯作者：
A. Luntz
中科院分区：
文献类型：
--
作者：
A. Luntz
Vibrational excitations of specific bonds in molecules have been used to enhance the reactivity of the molecules in direct gas-phase reactions. In his Perspective, Luntz highlights a report by Beck et al., who show that such vibrational control may also be possible for catalytic reactions at a surface. The authors demonstrate that differently excited deuterated methane molecules have different dissociation probabilities on a nickel surface, even though the energies of the different molecules are similar.
