Solution processable hydrogen-bonded perylene bisimide assemblies organizing into lamellar architectures.
Solution processable hydrogen-bonded perylene bisimide assemblies organizing into lamellar architectures.
复制标题
DOI：
10.1039/c1cc15118e
复制
发表时间：
2011-11
影响因子：
4.9
通讯作者：
T. Seki;Yukihiro Maruya;K. Nakayama;T. Karatsu;Akihide Kitamura;S. Yagai
中科院分区：
文献类型：
--
作者：
T. Seki;Yukihiro Maruya;K. Nakayama;T. Karatsu;Akihide Kitamura;S. Yagai
带有燕尾烷基链的二萘嵌苯双酰亚胺的双位三聚氰胺可以通过与互补氢键合的巴比妥酸盐或氰尿酸盐混合而溶解在有机溶剂中，形成可溶液加工的超分子组装体。在旋涂组件时，通过热退火形成高度组织化的层状结构，其充当有机场效应晶体管中的电子传输层。
A ditopic melamine bearing perylene bisimides with swallow-tail alkyl chains can be dissolved in organic solvents by mixing with complementary hydrogen-bonding barbiturate or cyanurate, forming solution processable supramolecular assemblies. Upon spin-coating the assemblies, highly organized lamellar architectures are formed with thermal annealing, which act as electron transporting layers in organic field effect transistors.