Direct Synthesis of Organic Azides from Primary Amines with 2-Azido-1,3-dimethylimidazolinium Hexafluorophosphate
Direct Synthesis of Organic Azides from Primary Amines with 2-Azido-1,3-dimethylimidazolinium Hexafluorophosphate
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DOI：
10.1002/ejoc.201001509
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发表时间：
2011-01-01
影响因子：
2.8
通讯作者：
Okauchi, Tatsuo
中科院分区：
文献类型：
--
作者：
Kitamura, Mitsuru;Yano, Masakazu;Okauchi, Tatsuo
以伯胺为原料，以2-叠氮-1,3-二甲基咪唑六氟磷酸为原料，采用无金属重氮转移法制备了有机叠氮化合物，该化合物是一种稳定、易处理的结晶固体。
Organic azides were prepared from primary amines in high yields by metal-free diazo transfer with 2-azido-1,3-dimethylimidazolinium hexafluorophosphate, which is a stable, crystalline solid that is easy to handle.