Dehydrogenative Silylation of Terminal Alkynes with Hydrosilanes under Zinc–Pyridine Catalysis
Dehydrogenative Silylation of Terminal Alkynes with Hydrosilanes under Zinc–Pyridine Catalysis
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DOI：
10.1002/adsc.201200310
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发表时间：
2012-11
影响因子：
5.4
通讯作者：
T. Tsuchimoto;Masakazu Fujii;Y. Iketani;Masaru Sekine
中科院分区：
文献类型：
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作者：
T. Tsuchimoto;Masakazu Fujii;Y. Iketani;Masaru Sekine
研究发现，三氟甲磺酸锌和吡啶在腈介质中的组合可作为一种有效的催化系统，用于末端炔烃和氢硅烷的柔性片段的脱氢硅烷化，从而以高至优异的产率生产各种炔基硅烷。
A combination of zinc triflate and pyridine in a nitrile medium was found to act as an effective catalytic system for dehydrogenative silylation with flexible pieces of terminal alkynes and hydrosilanes, thereby producing diverse alkynylsilanes in high to excellent yields.