Ferroelectric Sm-doped BiMnO3 thin films with ferromagnetic transition temperature enhanced to 140 K.
Ferroelectric Sm-doped BiMnO3 thin films with ferromagnetic transition temperature enhanced to 140 K.
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DOI:
10.1021/am501351c
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发表时间:
2014-09-10
影响因子:
9.5
通讯作者:
MacManus-Driscoll, Judith L.
中科院分区:
文献类型:
--
作者:
Choi, Eun-Mi;Kursumovic, Ahmed;Lee, Oon Jew;Kleibeuker, Josee E.;Chen, Aiping;Zhang, Wenrui;Wang, Haiyan;MacManus-Driscoll, Judith L.
A combined chemical pressure and substrate biaxial pressure crystal engineering approach was demonstrated for producing highly epitaxial Sm-doped BiMnO3 (BSMO) films on SrTiO3 single crystal substrates, with enhanced magnetic transition temperatures, TC up to as high as 140 K, 40 K higher than that for standard BiMnO3 (BMO) films. Strong room temperature ferroelectricity with piezoresponse amplitude, d33 = 10 pm/V, and long-term retention of polarization were also observed. Furthermore, the BSMO films were much easier to grow than pure BMO films, with excellent phase purity over a wide growth window. The work represents a very effective way to independently control strain in-plane and out-of-plane, which is important not just for BMO but for controlling the properties of many other strongly correlated oxides.
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