Stability of Diels-Alder photoadducts in macromolecules
Stability of Diels-Alder photoadducts in macromolecules
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DOI：
10.1039/c8py00748a
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发表时间：
2018-07
影响因子：
4.6
通讯作者：
C. Petit;Lukas D Bangert;M. Abbasi;M. Wilhelm;Anja S. Goldmann;C. Barner‐Kowollik
中科院分区：
文献类型：
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作者：
C. Petit;Lukas D Bangert;M. Abbasi;M. Wilhelm;Anja S. Goldmann;C. Barner‐Kowollik
我们探索了由流行的光诱导狄尔斯-阿尔德反应产生的基于邻醌二甲烷的连接点的稳定性，评估它们承受挑战性环境的能力。我们的分子评估包括尺寸排阻色谱法以及高分辨率电喷雾电离质谱法 (SEC-HR ESI MS)，发现它们的稳定性取决于大分子链长度。
We explore the stability of o-quinodimethane-based ligation points generated by a popular photo-induced Diels–Alder reaction, assessing their ability to withstand challenging environments. Our molecular assessment includes size-exclusion chromatography as well as high resolution electrospray ionization mass spectrometry (SEC-HR ESI MS), finding that their stability is dependent on the macromolecular chain length.