Heterodinuclear Group 13 Element Complexes of N4O6-Type Dipyrrin with an Unsymmetrical Twisted Structure
Heterodinuclear Group 13 Element Complexes of N4O6-Type Dipyrrin with an Unsymmetrical Twisted Structure
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不对称扭曲结构N4O6型双吡啶异双核13族元素配合物
DOI：
10.1002/ejic.201801062
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发表时间：
2019
影响因子：
2.3
通讯作者：
and Tatsuya Nabeshima
中科院分区：
文献类型：
--
作者：
Makoto Saikawa;Takumu Noda;Ryota Matsuoka;Takashi Nakamura;and Tatsuya Nabeshima
通过与硼和13族元素(Al、Ga、In)的分步反应，合成了一种N4O6型联吡咯环二聚体的异双核13族元素络合物。大循环有一种新型的非对称扭曲(伪八字形)结构。
Heterodinuclear group 13 element complexes of an N4O6‐type dipyrrin cyclic dimer were synthesized by the stepwise reaction with boron and group 13 elements (Al, Ga, and In). The macrocycles have a new type of unsymmetrical twisted (pseudo‐figure‐of‐eight) structure.