Membrane reactor for acceleration of esterification using a special ionic liquid with reaction and separation and microwave heating
Membrane reactor for acceleration of esterification using a special ionic liquid with reaction and separation and microwave heating
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DOI:
10.1016/j.cattod.2012.03.020
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发表时间:
2012-10
期刊:
影响因子:
5.3
通讯作者:
T. Uragami;J. Kishimoto;T. Miyata
中科院分区:
文献类型:
--
作者:
T. Uragami;J. Kishimoto;T. Miyata
To improve conversion of n-butanol to the corresponding ester using acetic acid, the ionic liquid 1-allyl-3-butylimidazolium bis(trifluoromethanesulfonyl)imide ([ABIM]TFSI), which does not dissolve in the water by-product, and poly(vinyl alcohol) (PVA) or PVA–TEOS (tetraethoxysilane) hybrid membranes were employed when using evapomeation (EV), along with microwave heating. The effect on the conversion of n-butanol of each individual process variable as well as that of all of the variables used in combination was investigated, and the characteristics of each approach are discussed.